Partial colony mortality reflects coral community dynamics: a fringing reef study near a small river in Okinawa, Japan     

Dikou A  van Woesik R 《Marine pollution bulletin》2006,52(3):269-280

The relative performance of (i) percent live cover, (ii) colony density, (iii) generic richness, (iv) partial colony mortality, and (v) colony size of hard corals were evaluated to determine which variables best discriminated the coral communities near a small river in Okinawa, Japan. An analysis of their variance was undertaken across a combination of sites at three depths, at increasing distance from a river's influence (Zatsun River). The river provides a periodic and localized input of sediment and fresh water to the adjacent coral reef; the effects of which we assume attenuate at increasing distance from the river mouth. The mean frequency of partially dead coral colonies (i.e., the proportion of live coral colonies that were partially dead) presented the clearest and most reliable response to river affect, and the power to discriminate among sites improved steadily with increasing depth. Spatial examination of the prevalence of partial mortality, regardless of how long ago the infliction occurred, provides a clear window to long-term processes involving population and community change and indeed the reef building capacity of the communities.  相似文献   

(Na,Ca)(Ti3+,Mg)Si2O6-clinopyroxenes at high pressure: influence of cation substitution on elastic behavior and phase transition     

Angela Ullrich  Ronald Miletich  Tonci Balic-Zunic  Lars Olsen  Fabrizio Nestola  Manfred Wildner  Haruo Ohashi 《Physics and Chemistry of Minerals》2010,37(1):25-43

A compressional study of (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxenes was carried out at high pressures between 10⁻⁴ and 10.2 GPa using in situ single-crystal X-ray diffraction, Raman spectroscopy and optical absorption spectroscopy. Compressional discontinuities accompanied by structural changes, in particular, the appearance of two distinct Ti³⁺–Ti³⁺ distances within the octahedral chains at 4.37 GPa, provide evidence for the occurrence of a phase transition in NaTi³⁺Si₂O₆. Equation-of-state parameters are K ₀ = 115.9(7) GPa with K′ = −0.9(3) and K ₀ = 102.7(8) GPa with K′ = 4.08(5) for the low- and high-pressure range, respectively. The transition involves a C2/c–P [`1] \overline{1} symmetry change, which can be confirmed by the occurrence of new modes in Raman spectra. Since no significant discontinuity in the evolution of the unit-cell volume with pressure has been observed, the transition appears to be second-order in character. The influence of the coupled substitution Na⁺Ti³⁺↔Ca²⁺Mg²⁺ on the static compression behavior and the structural stability has been investigated using a sample of the intermediate composition (Na_0.54Ca_0.46)(Mg_0.46Ti_0.54)Si₂O₆. No evidence for a deviation from continuous compression behavior has been found, neither in lattice parameter nor in structural data and the fit of a third-order Birch–Murnaghan equation-of-state to the pressure–volume data yields a bulk modulus of K ₀ = 109.1(5) GPa and K′ = 5.02(13). Raman and polarized absorption spectra have been compared to NaTiSi₂O₆ and reveal major similarities. The main driving force for the phase transition in NaTi³⁺Si₂O₆ is the localization of the Ti³⁺ d-electron and the accompanying distortion, which is suppressed in the (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxene.  相似文献   

Crystal chemistry, surface morphology and X-ray photoelectron spectroscopy of Fe-rich osumilite from Mt. Arci, Sardinia (Italy)     

Chiara Elmi  Maria Franca Brigatti  Luca Pasquali  Monica Montecchi  Angela Laurora  Daniele Malferrari  Stefano Nannarone 《Physics and Chemistry of Minerals》2010,37(8):561-569

Microprobe analysis, single crystal X-ray diffraction, X-ray photoelectron spectroscopy, atomic force microscopy, and X-ray absorption spectroscopy were applied on Fe-rich osumilite from the volcanic massif of Mt. Arci, Sardinia, Italy. Osumilite belongs to the space group P6/mcc with unit cell parameters a = 10.1550(6), c = 14.306(1) Å and chemical formula (K_0.729)_C (Na_0.029)_B (Si_10.498 Al_1.502)_T1 (Al_2.706 Fe _0.294 ²⁺ )_T2 (Mg_0.735 Mn_0.091 Fe _1.184 ²⁺ )_AO₃₀. Structure refinement converged at R = 0.0201. Unit cell parameter a is related to octahedral edge length as well as to Fe²⁺ content, unlike the c parameter which does not seem to be affected by chemical composition. The determination of the amount of each element on the mineral surface, obtained through X-ray photoelectron spectroscopy high-resolution spectra in the region of the Si_2p, Al_2p, Mg_1s and Fe_2p core levels, suggests that Fe presents Fe²⁺ oxidation state and octahedral coordination. Two peaks at 103.1 and 100.6 eV can be related to Si⁴⁺ and Si¹⁺ components, respectively, both in tetrahedral coordination. The binding energy of Al_2p, at 74.5 eV, indicates that Al is mostly present in the distorted T2 site, whereas the Mg peak at 1,305.2 eV suggests that this cation is located at the octahedral site. X-ray absorption at the Fe L_2,3-edges confirms that iron is present in the mineral structure, prevalently in the divalent state and at the A octahedral site.  相似文献   

Socio-structural forces predicting global water footprint: socio-hydrology and ecologically unequal exchange     

Md Belal Hossain  Angela G. Mertig 《水文科学杂志》2020,65(4):495-506

ABSTRACT

Growth in water use and threatened shortages of water have become increasingly important in the modern world system. Natural resources are exploited extensively by capitalist interests in industrially advanced nations, while the lower strata of the world system, the underdeveloped societies, are left with limited access to natural resources for their productive processes, particularly water resources. We contribute to socio-hydrological research by examining underlying socio-structural factors that play a part in the process of deteriorating conditions of global water resources. Drawing on a world-systems perspective, this study examines how socio-structural forces – world-system position, per capita beef consumption, per capita energy consumption, and urbanization – affect per capita water footprint, which includes an accounting of “virtual water” consumption. We find that per capita beef consumption and per capita energy consumption have significant positive direct effects, and the world-system position has a significant indirect and total effect on per capita water footprint.  相似文献   

Application of the grid square technique to mapping of evapotranspiration     

Angela M. Foyster 《Journal of Hydrology》1973,19(3):205-226

A grid-based technique for mapping potential evapotranspiration is described. An attempt is made to extrapolate the constituent parameters of Penman's equation (1962) over a grid, so that the equation can be evaluated for every grid square. Data for a part of Southwest England are used to demonstrate the technique. Aspect and slope, which determine evaporation to a considerable degree, have been included using a formula derived by Okanoue.  相似文献   

Speciation and role of iron in cloud droplets at the puy de Dôme station     

Marius Parazols  Angela Marinoni  Pierre Amato  Otman Abida  Paolo Laj  Gilles Mailhot 《Journal of Atmospheric Chemistry》2006,54(3):267-281

Iron is the most abundant transition metal in the atmosphere and can play a significant role in cloudwater chemistry where its reactivity is closely related to the partitioning between Fe(II) and Fe(III). The objective of this work is to determine the total iron content and the iron speciation in a free tropospheric site, and to understand which factors influence these parameters. We collected 147 samples of cloudwater during 34 cloud events over a period of four years at the puy de Dôme summit. Besides iron we measured other chemical compounds, solar radiation, physico-chemical and meteorological parameters potentially connected with iron reactivity. The total iron concentrations ranged from 0.1 to 9.1 μM with the major frequency occurring at low levels. The pH and presence of organic complexants seem to be the most significant factors connected with total dissolved iron; while the iron oxidation state seems to be an independent factor. Light intensity, presence of complexants or oxidants (H₂O₂) do not influence the Fe(II)/Fe(Total) ratio, that was quite constant at about 0.75. This could be due to the potential redox that forces the Fe(II)-Fe(III) couple to the reduced form or, more probably to the complexation by Natural Organic Matter, that can stabilize iron in its reduced form and prevent further oxidation. Our field measurements did not show the diurnal cycle observed in surface water and predicted by models of atmospheric chemistry. This result prompts a more careful review of the role of iron and, by analogy, all the transition metals in atmospheric liquid phase, often over-estimated in the literature.  相似文献   

A Wetland Simulation Module for the MODFLOW Ground Water Model   总被引：8，自引：0，他引：8  

Jorge I. Restrepo  Angela M. Montoya  Jayantha Obeysekera 《Ground water》1998,36(5):764-770

  相似文献   

Absolute dating by uranium series disequilibrium of bones from the cave of La Chaise-de-Vouthon (Charente), France     

Angela M. Rae  Miro Ivanovich  Henry P. Schwarcz 《地球表面变化过程与地形》1987,12(5):543-550

Animal bones, associated with Palaeolithic artefacts and skeletal remains of early hominids from the cave of La Chaise-de-Vouthon, have been dated using a new approach to uranium series dating of bone. Speleothem (cave calcite) interstratified with bone-bearing sediments in the two chambers of Grotte Bourgeois-Delaunay and Grotte Suard have previously been dated by the ²³⁰Th/²³⁴ U method. This provides a chronological control for the bone ages, for which the method is still at an experimental stage. A good agreement is shown in most cases between the calcite and the bone ages, showing the cave to have been a stable environment for the deposition of bone and the acquisition of uranium.  相似文献   

Origin and significance of 13-hydroxychlorophyll derivatives in sediments     

J Stuart Walker  Angela H Squier  Dominic A Hodgson  Brendan J Keely   《Organic Geochemistry》2002,33(12)

The authenticity of hydroxychlorophyll derivatives in sediments has been verified by subjecting pure chlorophyll preparations to the extraction method used for sediments. Model studies of chlorophyll autoxidation reveal hydroxychlorophyll as the major product formed in the presence of hydrogen peroxide. Its stability to further oxidation implies that hydroxychlorophyll derivatives are not precursors of aetioporphyrins and are more likely to produce cycloalkanoporphyrins via the processes of diagenesis. The occurrence of 13²-hydroxyphaeophytin a throughout a sediment core from Loch Ness confirms it to be a widespread chlorophyll oxidation product formed during early diagenesis. Profiles of hydroxychlorophyll derivatives in a sediment core from an Antarctic lake demonstrate their potential for use as markers of oxidation processes in palaeoenvironmental assessment.  相似文献   

The dual isotopes of deep nitrate as a constraint on the cycle and budget of oceanic fixed nitrogen   总被引：1，自引：0，他引：1  

Daniel M. Sigman  Peter J. DiFiore  Mathis P. Hain  Curtis Deutsch  Yi Wang  David M. Karl  Angela N. Knapp  Moritz F. Lehmann  Silvio Pantoja 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(9):1419-1439

We compare the output of an 18-box geochemical model of the ocean with measurements to investigate the controls on both the mean values and variation of nitrate δ¹⁵N and δ¹⁸O in the ocean interior. The δ¹⁸O of nitrate is our focus because it has been explored less in previous work. Denitrification raises the δ¹⁵N and δ¹⁸O of mean ocean nitrate by equal amounts above their input values for N₂ fixation (for δ¹⁵N) and nitrification (for δ¹⁸O), generating parallel gradients in the δ¹⁵N and δ¹⁸O of deep ocean nitrate. Partial nitrate assimilation in the photic zone also causes equivalent increases in the δ¹⁵N and δ¹⁸O of the residual nitrate that can be transported into the interior. However, the regeneration and nitrification of sinking N can be said to decouple the N and O isotopes of deep ocean nitrate, especially when the sinking N is produced in a low latitude region, where nitrate consumption is effectively complete. The δ¹⁵N of the regenerated nitrate is equivalent to that originally consumed, whereas the regeneration replaces nitrate previously elevated in δ¹⁸O due to denitrification or nitrate assimilation with nitrate having the δ¹⁸O of nitrification. This lowers the δ¹⁸O of mean ocean nitrate and weakens nitrate δ¹⁸O gradients in the interior relative to those in δ¹⁵N. This decoupling is characterized and quantified in the box model, and agreement with data shows its clear importance in the real ocean. At the same time, the model appears to generate overly strong gradients in both δ¹⁸O and δ¹⁵N within the ocean interior and a mean ocean nitrate δ¹⁸O that is higher than measured. This may be due to, in the model, too strong an impact of partial nitrate assimilation in the Southern Ocean on the δ¹⁵N and δ¹⁸O of preformed nitrate and/or too little cycling of intermediate-depth nitrate through the low latitude photic zone.  相似文献